Source identification of PM_2.5 particles measured in Gwangju, Korea   总被引：1，自引：0，他引：1  

Hanlim Lee  Seung S. Park  Kyung W. Kim  Young J. Kim   《Atmospheric Research》2008,88(3-4):199-211

The UNMIX and Chemical Mass Balance (CMB) receptor models were used to investigate sources of PM_2.5 aerosols measured between March 2001 and February 2002 in Gwangju, Korea. Measurements of PM_2.5 particles were used for the analysis of carbonaceous species (organic (OC) and elemental carbon (EC)) using the thermal manganese dioxide oxidation (TMO) method, the investigation of seven ionic species using ion chromatography (IC), and the analysis of twenty-four metal species using Inductively Coupled Plasma (ICP)-Atomic Emission Spectrometry (AES)/ICP-Mass Spectrometry (MS). According to annual average PM_2.5 source apportionment results obtained from CMB calculations, diesel vehicle exhaust was the major contributor, accounting for 33.4% of the measured PM_2.5 mass (21.5 μg m^− 3), followed by secondary sulfate (14.6%), meat cooking (11.7%), secondary organic carbon (8.9%), secondary nitrate (7.6%), urban dust (5.5%), Asian dust (4.4%), biomass burning (2.8%), sea salt (2.7%), residual oil combustion (2.6%), gasoline vehicle exhaust (1.9%), automobile lead (0.5%), and components of unknown sources (3.4%). Seven PM_2.5 sources including diesel vehicles (29.6%), secondary sulfate (17.4%), biomass burning (14.7%), secondary nitrate (12.6%), gasoline vehicles (12.4%), secondary organic carbon (5.8%) and Asian dust (1.9%) were identified from the UNMIX analysis. The annual average source apportionment results from the two models are compared and the reasons for differences are qualitatively discussed for better understanding of PM_2.5 sources.Additionally, the impact of air mass pathways on the PM_2.5 mass was evaluated using air mass trajectories calculated with the Hybrid Single-Particle Lagrangian Integrated Trajectory (HYSPLIT) backward trajectory model. Source contributions to PM_2.5 collected during the four air mass patterns and two event periods were calculated with the CMB model and analyzed. Results of source apportionment revealed that the contribution of diesel traffic exhaust (47.0%) in stagnant conditions (S) was much higher than the average contribution of diesel vehicle exhaust (33.4%) during the sampling period. During Asian dust (AD) periods when the air mass passed over the Korean peninsula, Asian dust and secondary organic carbon accounted for 25.2 and 23.0% of the PM_2.5 mass, respectively, whereas Asian dust contributed only 10.8% to the PM_2.5 mass during the AD event when the air mass passed over the Yellow Sea. The contribution of biomass burning to the PM_2.5 mass during the biomass burning (BB) event equaled 63.8%.  相似文献   

Source attribution of urban smog episodes caused by coal combustion   总被引：1，自引：0，他引：1  

D. Mira-Salama  C. Grüning  N.R. Jensen  P. Cavalli  J.-P. Putaud  B.R. Larsen  F. Raes  H. Coe 《Atmospheric Research》2008,88(3-4):294-304

Stable weather conditions together with extensive use of coal combustion often lead to severe smog episodes in certain urban environments, especially in Eastern Europe. In order to identify the specific sources that cause the smog episodes in such environments, and to better understand the mixing state and atmospheric processing of aerosols, both single particle and bulk chemical characterization analysis of aerosols were performed in Krakow, Poland, during winter 2005.Real-time measurements of the bulk PM10 aerosol during a severe smog episode (PM10 mass > 400 µg m^− 3) showed a stable concentration of black carbon in the aerosol, and an increase in the sulphate and chlorine mass contributions towards the end of the episode. Chemical characterization of single particles further helped to identify residential coal burning as the main source that caused this severe smog episode, consisting of single particles with major signals for carbon with simultaneous absence of sulphate, chlorine and calcium. Particles from industrial coal combustion gained importance towards the end of that episode, after residential coal combustion was switched off, indicated by an increase of the percentage of sulphate and chlorine containing particles. Traffic was not a significant source during the severe smog episode. During a lighter smog episode, residential and industrial coal combustion was still predominant, with an increased contribution of traffic and processed/aged aerosols. On a clean day, particle classes containing nitrate were the most abundant. In addition, the aerosol was more internally mixed showing that there were more sources contributing to the total aerosol population.  相似文献   

秸秆焚烧导致的江苏持续雾霾天气过程分析   总被引：3，自引：2，他引：1  

严文莲  刘端阳  孙燕  魏建苏  濮梅娟 《气候与环境研究》2014,19(2):237-247

利用常规观测资料和NCEP再分析资料,从污染情况、环流背景、地面气象要素特征、水汽、热力及动力条件等几个方面对江苏2012年6月中上旬持续雾霾天气进行了分析。结果表明:江苏及周边省市秸秆焚烧造成大量的气溶胶粒子悬浮于空中,是造成江苏出现持续不同程度的霾天气的主要原因,同时也为雾滴形成提供了丰富的凝结核;中高层冷空气强度未能完全破坏底层相对稳定的层结,较小的风速和较大的湿度有利于雾霾的发展,重度霾或雾风速多在3 m/s以下,且相对湿度在80%以上。频繁的弱降水过程对雾的形成和霾的加重起到了重要的作用;低层的逆温或近中性层结的维持,为雾霾持续存在提供了有利的层结条件,且浓雾形成主要有辐射贴地逆温和平流逆温两种形式;垂直上升运动与雾霾的发展之间有着互相影响的紧密联系,在具备一定的水汽条件时,底层弱的上升运动有利于雾体的向上发展从而促进雾的加浓。后向轨迹模拟雾霾相对较严重的6月10日污染轨迹表明沿江和苏南地区污染物浓度上升除了本地悬浮颗粒物外,安徽境内的污染物的输送也是一个重要因素,而北部地区更多还是本地的污染源。  相似文献   

华北板块东南缘海相层系演化特征及油气远景          下载免费PDF全文

柳忠泉 《沉积与特提斯地质》2009,29(1):37-45

在大别造山带内发现的可燃天然气和发生燃烧的隧道具有明显的区域性,集中分布于磨子潭-晓天断裂以南的北大别杂岩带和信阳-舒城断裂附近的早石炭世变质石英片岩中,磨子潭-晓天断裂和信阳。舒城断裂是连通深部的气源通道断裂;推覆体之下的下寒武统凤台组和北淮阳型石炭系两套海相烃源岩是隧道可燃天然气的主力气源岩,其中下寒武统凤台组属大陆边缘沉积,其发育的海相泥质烃源岩具有高碳,高“R。”,高T…和低氯仿“A”的特点,已进入热演化的过成熟阶段;北淮阳型石炭系处于前陆盆地的沉积中心,地层序列齐全,其煤系源岩有机质丰度高,以Ⅲ型干酪根为主,热演化程度很高,大量的油气已经生成,最重要的是研究其成烃过程与圈闭配套史的关系。大别造山带隧道可燃天然气的发现展示了合肥盆地区深部海相层系可能潜在良好的勘探前景。因此,进一步勘探重心应从“中新生代盆地系统”转移到“深部海相层系”,以寻找“古生古储”或“古生新储”类型油气藏为主。  相似文献   

河北蔚县煤田下花园组成煤植物初探     

张树胜 《中国煤炭地质》2009,(7):12-14

通过对蔚县煤田下花园组煤中植物残体——分散角质层、半丝炭化木材等研究,结合非煤层中植物化石和孢粉组合特征分析,认为泥炭沼泽植物群落主要由松柏类、银杏类、苏铁类和蕨类组成,它们都是本区成煤的重要物质来源。这种森林体系代表了一种温暖潮湿、雨量充沛的古气候条件。煤中丝炭及半丝炭化组分含量丰富是泥炭堆积速度快于盆地基底沉降速度,并最终导致泥炭沼泽覆水浅,泥炭层多处于相对干燥、氧化环境的表现。不同煤层中丝炭及半丝炭化组分含量的差异,为煤层对比提供了新的依据。  相似文献   

分形插值与传统插值相结合的方法研究   总被引：9，自引：0，他引：9  

范玉红  栾元重  王永  梁青科  王国现 《测绘科学》2005,30(2):76-77,80

本文针对测量数据提出了基于分形的线性插值 ,该法综合了分形插值理论和传统线性插值理论的优点。算例表明 :该法优于单一的分形插值和单一的线形插值 ,后验差检验法表明插值结果优等  相似文献   

Temporal-spatial Distribution of Suitable Areas for Major Food Crops in China Over 60 Years     

Xiaoju Ning  Lijun Zhang  Yaochen Qin  Kai Liu 《地球科学进展》2019,34(2):191-201

Simulating the temporal-spatial distribution of areas suitable for crops is an important part of analyzing the effects of climate change on crop growth, reducing the vulnerability of crop growth, and assessing the adaptability of crop growth to climate change. This study selected climate factors that affect the growth of wheat, maize and rice, and it combined surface soil and ground elevation factors as environment variables, as well as data from agricultural observation stations as species variables. The MaxEnt ecological model was used to identify suitable areas for these three crops during the period of 1953-2012. The areas suitable for the three crops were analyzed to determine the temporal-spatial distribution of major food crops and to estimate the difference in crop growth adaptability under climate change. The results showed the following: \mathrm{①} The response to climate change of the areas suitable for food crops could be ranked from strongest to weakest as follows: wheat, rice, and maize. \mathrm{②} On the same space-time scale, for the growth of wheat and rice, the southern agricultural regions, mountainous areas and plateaus were relatively unsuitable for a wider variety of crops than the northern agricultural regions, plains and basins. \mathrm{③} The adaptability of wheat increased in the major agricultural regions slightly. The adaptability of maize increased in the northern agricultural regions and decreased in the southern agricultural regions, respectively. The adaptability of rice was stable in the southern agricultural regions, and it decreased in the Huang-Huai-Hai region and increased in the northeastern region. \mathrm{④} Over 60 years, the ability of the major food crops to adapt to climate change increased in the northeast region, Gansu-Xinjiang region, Southwest region and Loess Plateau region, but the adaptability of major food crops decreased in the Huang-Huai-Hai region and the Mid-and-Lower Reaches of the Yangtze River. \mathrm{⑤} The suitable areas of maize and rice were significantly correlated with planting areas and yields, respectively, which provided feasibility for simulating the distribution of suitable areas on maize and rice in different climate scenarios in the future. The suitable area of wheat is not significantly related to the planting area and yield. In the future, we will take more factors to model the suitable area of wheat accurately.  相似文献   

作物产量与土壤环境的关系   总被引：11，自引：1，他引：10  

曾昭华 《湖南地质》2000,19(1):25-29

作物的产量与土壤元素中Ｎ、Ｐ、Ｋ、Ｎａ、Ｃａ、Ｍｇ、Ｓ、Ｆｅ、Ｍｎ、Ｃｕ、Ｚｎ、Ｂ、Ｍｏ、Ｖ、Ｃｏ、Ｎｉ、Ｃｒ、Ｐｂ、Ｃｄ、Ｈｇ、Ｓｅ、Ｆ、ＴＩ、Ｂａ、Ｔｅ、Ｔａ、Ｓｒ、Ｔｉ、Ｓｉ等元素及稀土、有机质、酸碱度和含水量、含盐量密切有关。  相似文献   

吉林省桦甸油页岩中稀土元素和微量元素的研究   总被引：5，自引：0，他引：5  

高桂梅  苏克  王文颖  甘树才  刘招君 《吉林大学学报(地球科学版)》2006,36(6):974-979

对桦甸油页岩及其灰渣的矿物成分、主量元素、稀土元素和微量元素含量进行测定。结果表明：油页岩中稀土元素含量低于北美页岩(NASC)中的平均含量,REE球粒陨石标准化的分布模式曲线表现为负斜率,(La/Yb)_N的平均值大于1,属于轻稀土富集型;REE北美页岩标准化的分布模式曲线较平缓,（La/Yb）_S的平均值接近于1,轻重稀土分馏不明显。与球粒陨石和北美页岩相比,Eu有较严重的正异常。油页岩中的微量元素与北美页岩和地壳的平均值相比较,Sb、Nb、Cs、Zn、Bi、W等元素具有较高的富集度。油页岩灰渣中稀土元素和微量元素富集度均高于油页岩。  相似文献   

Response of Spartina alterniflora Vegetation to Oiling and Burning of Applied Oil     

C.W Lindau  R.D Delaune  A Jugsujinda  E Sajo 《Marine pollution bulletin》1999,38(12):781-1220

A field study evaluated Spartina alterniflora sensitivity to oiling and to in situ burning of applied crude oil. Experimental plots (2.4 m × 2.4 m × 0.6 m) were constructed in the salt marsh for control, oiling (natural clean-up) and oiling/burning treatments. South Louisiana Crude was applied to oiling and oiling/burning treatment plots at 2 l m⁻² and the burn conducted. S. alterniflora responses (height, live stem density, carbon fixation and biomass) were measured for 50 weeks after the August burn. Oiling and oiling/burning had short-term detrimental effects on the salt marsh. One year after the late summer burn, S. alterniflora responses measured in the oiled and oiled/burned plots were not significantly different compared to control values. Results suggest that, under our experimental conditions, intervention may not be required for marsh recovery. However, if spill conditions require a rapid response to control contaminant spread or protect other sensitive resources, burning may be a clean-up operation to consider.  相似文献